Iran’s Small and Medium Enterprises (SMEs) have been widely introduced in the market these days. In the emerging trend of electronic data interchange, Iran’s political, economical and social issues have been diverted to a more aggressive approach to the world of e-commerce, that despite the shadowing issues of the past, Iran already internalized the promising craft of e-commerce through various IT adoption techniques and skills. In line with this, this study is aimed to the growing emergence on Iran’s SMEs and how e-commerce contributes to the success of IT adoption. (Ajdari, 2007).This paper would further identify the ways and reasons how Iran thrived to its current status as a raising e-commerce country (Powers and Carvar, 1990) It’s the main responsibility of governmental forces to enable organizational and national forces to gain dynamic control over resources and markets for a better e-Commerce take off (Moor & Benbasat, I996). Also, we will investigate fifty SMEs and surveys along with personal interviews will be conducted to locate findings, reasons, causes and effects in this regard. Study will focus on three main areas of SMEs including organizational, environmental and technological aspects. Results indicate the significant perceived value of government support in SMEs development in Iran (Dearing, 1990).